Nickel-Catalyzed Efficient and Practical Suzuki−Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines

Suzuki−Miyaura coupling of unactivated alkenyl carbamates is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.

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Bibliographische Detailangaben
Veröffentlicht in:	Organic letters 2010-02, Vol.12 (4), p.884-887
Hauptverfasser:	Xu, Li, Li, Bi-Jie, Wu, Zhen-Hua, Lu, Xing-Yu, Guan, Bing-Tao, Wang, Bi-Qin, Zhao, Ke-Qing, Shi, Zhang-Jie
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemical synthesis Alkenes - chemistry Boron Compounds - chemistry Carbamates - chemical synthesis Carbamates - chemistry Catalysis Combinatorial Chemistry Techniques Molecular Structure Nickel - chemistry
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Beschreibung
Zusammenfassung:	Suzuki−Miyaura coupling of unactivated alkenyl carbamates is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol9029534