Barium bis­[6-amino-3-methyl-5-nitro­so­pyrimidine-2,4(1H,3H)-dionate] trihydrate: coordination polymer chains linked by hydrogen bonds

Barium bis­[6-amino-3-methyl-5-nitro­so­pyrimidine-2,4(1H,3H)-dionate] trihydrate: coordination polymer chains linked by hydrogen bonds

The title complex, catena‐poly[[triaquabarium(II)]‐di‐μ‐6‐amino‐3‐methyl‐5‐nitro­so­pyrimidine‐2,4(1H,3H)‐dionato], [Ba(C5H5N4O3)2(H2O)3]n, forms a coordination polymer chain in which the two distinct anions use different ligating atoms to bridge pairs of cations. Adjacent pairs of cations are also...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-06, Vol.59 (6), p.m255-m258
Hauptverfasser: López Garzón, Rafael, Godino Salido, M. Luz, Low, John N., Glidewell, Christopher
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Zusammenfassung:The title complex, catena‐poly[[triaquabarium(II)]‐di‐μ‐6‐amino‐3‐methyl‐5‐nitro­so­pyrimidine‐2,4(1H,3H)‐dionato], [Ba(C5H5N4O3)2(H2O)3]n, forms a coordination polymer chain in which the two distinct anions use different ligating atoms to bridge pairs of cations. Adjacent pairs of cations are also linked by pairs of bridging water mol­ecules. The chains are linked into a single three‐dimensional framework by an extensive series of hydrogen bonds.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103009703