Chlorido(eta(5)-cyclopentadienyl)bis(dimethylamido)titanium, [TiCl(eta5-C5H5)(NMe2)2]

Chlorido(eta(5)-cyclopentadienyl)bis(dimethylamido)titanium, [TiCl(eta5-C5H5)(NMe2)2]

The title complex, [Ti(C(5)H(5))(C(2)H(6)N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti-->cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclo...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2010-07, Vol.66 (Pt 7), p.m191-m193
Hauptverfasser: Chapin, Brette M, Hughs, Lauren D, Golen, James A, Rheingold, Arnold L, Johnson, Adam R
Format: Artikel
Sprache:eng
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Zusammenfassung:The title complex, [Ti(C(5)H(5))(C(2)H(6)N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti-->cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.
ISSN:1600-5759
DOI:10.1107/S0108270110023176