Neutral Flavins: Green and Robust Organocatalysts for Aerobic Hydrogenation of Olefins

Neutral Flavins: Green and Robust Organocatalysts for Aerobic Hydrogenation of Olefins

Various olefins can be hydrogenated quantitatively with neutral flavin 2 catalysts in the presence of 1−2 equiv of hydrazine under 1 atm of O2. Vitamin B2 derivative 2g acts as a highly efficient and robust catalyst for the present environmentally benign process producing water and nitrogen gas as t...

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Veröffentlicht in:Organic letters 2010-01, Vol.12 (1), p.32-35
Hauptverfasser: Imada, Yasushi, Kitagawa, Takahiro, Ohno, Takashi, Iida, Hiroki, Naota, Takeshi
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes - chemistry
Catalysis
Flavins - chemistry
Hydrazines - chemistry
Hydrogenation
Molecular Structure
Nitrogen - chemistry
Oxygen - chemistry
Water
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Zusammenfassung:Various olefins can be hydrogenated quantitatively with neutral flavin 2 catalysts in the presence of 1−2 equiv of hydrazine under 1 atm of O2. Vitamin B2 derivative 2g acts as a highly efficient and robust catalyst for the present environmentally benign process producing water and nitrogen gas as the only waste products.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol902393p