Pt(II) N-confused porphyrin: an expanded pyrrole that affords a stable pi-anion

Pt(II) N-confused porphyrin: an expanded pyrrole that affords a stable pi-anion

Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl(-), Br(-), and I(-) anions at the peripheral N-H, while deprotonation proceeds with F(-), H(2)PO(4)(-), and OH(-) in CH(2)Cl(2) solution; neutral and anionic structures of 1-Pt were characterized by s...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (31), p.6151-6158
Hauptverfasser: Won, Dong-Hoon, Toganoh, Motoki, Uno, Hidemitsu, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
Schlagworte:
Anions - chemistry
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Platinum - chemistry
Porphyrins - chemistry
Pyrroles - chemistry
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Zusammenfassung:Pt(II) complex of meso-tetrakis(pentafluorophenyl) N-confused porphyrin (1-Pt) efficiently binds Cl(-), Br(-), and I(-) anions at the peripheral N-H, while deprotonation proceeds with F(-), H(2)PO(4)(-), and OH(-) in CH(2)Cl(2) solution; neutral and anionic structures of 1-Pt were characterized by single crystal X-ray diffraction analysis.
ISSN:1477-9226
1477-9234
DOI:10.1039/b906018a