Changing the local coordination environment in mono- and bi- nuclear lanthanide complexes through "click" chemistry

Changing the local coordination environment in mono- and bi- nuclear lanthanide complexes through "click" chemistry

Alkyne appended lanthanide complexes derived from DO3A undergo copper catalysed cycloaddition reactions with azides to form triazole appended complexes: coordination of one of the triazole nitrogen atoms to the metal centre changes the local coordination environment and the spectroscopic properties...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (32), p.6283-6285
Hauptverfasser: Jauregui, Maite, Perry, William S, Allain, Clémence, Vidler, Lewis R, Willis, Michael C, Kenwright, Alan M, Snaith, John S, Stasiuk, Graeme J, Lowe, Mark P, Faulkner, Stephen
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Sprache:eng
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Zusammenfassung:Alkyne appended lanthanide complexes derived from DO3A undergo copper catalysed cycloaddition reactions with azides to form triazole appended complexes: coordination of one of the triazole nitrogen atoms to the metal centre changes the local coordination environment and the spectroscopic properties of the complex.
ISSN:1477-9226
1477-9234
DOI:10.1039/b911588a