Mechanisms of C-H bond activation: rich synergy between computation and experiment

Mechanisms of C-H bond activation: rich synergy between computation and experiment

Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activa...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2009-01 (30), p.5820-5831
Hauptverfasser: Boutadla, Youcef, Davies, David L, Macgregor, Stuart A, Poblador-Bahamonde, Amalia I
Format: Artikel
Sprache:eng
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Zusammenfassung:Recent computational studies of C-H bond activation at late transition metal systems are discussed and processes where lone pair assistance via heteroatom co-ligands or carboxylates are highlighted as a particularly promising means of cleaving C-H bonds. The term 'ambiphilic metal ligand activation' (AMLA) is introduced to describe such reactions.
ISSN:1477-9226
1477-9234
DOI:10.1039/b904967c