Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)

Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al)

The MIXMOF concept has been applied to the metal-organic framework compound MIL-53(Al). The random incorporation of two different linker molecules (benzene-1,4-dicarboxylate and 2-aminobenzene-1,4-dicarboxylate) in the framework structure and its influence on thermal stability were proven using seve...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (16), p.3795-3798
Hauptverfasser: Marx, Stefan, Kleist, Wolfgang, Huang, Jun, Maciejewski, Marek, Baiker, Alfons
Format: Artikel
Sprache:eng
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Zusammenfassung:The MIXMOF concept has been applied to the metal-organic framework compound MIL-53(Al). The random incorporation of two different linker molecules (benzene-1,4-dicarboxylate and 2-aminobenzene-1,4-dicarboxylate) in the framework structure and its influence on thermal stability were proven using several complementary techniques (XRD, ATR-IR, MAS-NMR and TG).
ISSN:1477-9226
1477-9234
DOI:10.1039/c002483j