Conformation-Selective Laser Chemistry

Conformation-Selective Laser Chemistry

Selection of a conformer by a laser pulse and conformation‐specific cleavage by a second laser pulse can be used to control the outcome of a chemical reaction. One of the most recent examples is the selective wavelength‐dependent generation of either the 2‐propyl cation or corner‐protonated cyclopro...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-05, Vol.42 (21), p.2336-2337
1. Verfasser: Goez, Martin
Format: Artikel
Sprache:eng
Schlagworte:
conformers
laser chemistry
molecular dynamics
photochemistry
rearrangement
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Beschreibung
Zusammenfassung:Selection of a conformer by a laser pulse and conformation‐specific cleavage by a second laser pulse can be used to control the outcome of a chemical reaction. One of the most recent examples is the selective wavelength‐dependent generation of either the 2‐propyl cation or corner‐protonated cyclopropane from 1‐iodopropane (see scheme).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200201626