Direct Functionalization of Polycyclic Aromatics via Radical Perfluoroalkylation

Direct Functionalization of Polycyclic Aromatics via Radical Perfluoroalkylation

Direct functionalization of electron-deficient and electron-rich polycyclic aromatics via copper-mediated radical perfluoroalkylation was achieved in high yields.

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Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2010-05, Vol.12 (10), p.2374-2377
Hauptverfasser: Li, Yan, Li, Cheng, Yue, Wan, Jiang, Wei, Kopecek, Ralf, Qu, Jianqiang, Wang, Zhaohui
Format: Artikel
Sprache:eng
Schlagworte:
Alkylation
Copper - chemistry
Crystallography, X-Ray
Electrons
Fluorocarbons - chemistry
Free Radicals - chemistry
Models, Molecular
Polycyclic Aromatic Hydrocarbons - chemistry
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Beschreibung
Zusammenfassung:Direct functionalization of electron-deficient and electron-rich polycyclic aromatics via copper-mediated radical perfluoroalkylation was achieved in high yields.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol1007197