Unprecedented Zinc-Borane Complexes

Unprecedented Zinc-Borane Complexes

A borane–borohydride and a borane–methyl zinc complex were synthesized by different synthetic pathways. In both compounds the borane molecule is κ1‐coordinated to the zinc atom (see figure).

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Veröffentlicht in:Chemistry : a European journal 2010-06, Vol.16 (24), p.7096-7100
Hauptverfasser: Marks, Sebastian, Köppe, Ralf, Panda, Tarun K., Roesky, Peter W.
Format: Artikel
Sprache:eng
Schlagworte:
boranes
borohydride
Chemistry
coordination compounds
coordination modes
zinc
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Beschreibung
Zusammenfassung:A borane–borohydride and a borane–methyl zinc complex were synthesized by different synthetic pathways. In both compounds the borane molecule is κ1‐coordinated to the zinc atom (see figure).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201000571