Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles

Palladium-Catalyzed Bissilylation of Arynes with Cyclic Disilanes:  Synthesis of Benzo-Annulated Disilacarbocycles

Arynes, generated in situ from 2-(trimethylsilyl)aryl triflate and a fluoride ion, were found to insert into a silicon−silicon bond of cyclic disilanes in the presence of a catalytic amount of a palladium−tert-alkyl isocyanide complex to afford diverse benzo-annulated disilacarbocycles straightforwa...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Chemical Society 2003-06, Vol.125 (22), p.6638-6639
Hauptverfasser: Yoshida, Hiroto, Ikadai, Junnai, Shudo, Miwa, Ohshita, Joji, Kunai, Atsutaka
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Arynes, generated in situ from 2-(trimethylsilyl)aryl triflate and a fluoride ion, were found to insert into a silicon−silicon bond of cyclic disilanes in the presence of a catalytic amount of a palladium−tert-alkyl isocyanide complex to afford diverse benzo-annulated disilacarbocycles straightforwardly in modest to high yields.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja034571d