Nucleophilic Phosphinidene Complexes: Access and Applicability

Nucleophilic Phosphinidene Complexes: Access and Applicability

Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM==P---R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transition-metal moieties. The differ...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-03, Vol.49 (12), p.2102-2113
Hauptverfasser: Aktaş, Halil, Slootweg, J. Chris, Lammertsma, Koop
Format: Artikel
Sprache:eng
Schlagworte:
carbene homologues
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Phosphines - chemical synthesis
Phosphines - chemistry
phosphinidene ligands
phosphorus
synthesis design
transition metals
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Zusammenfassung:Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM==P---R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transition-metal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200905689