A Versatile and Highly Reactive Polyfluorinated Hypervalent Iodine(III) Compound

A Versatile and Highly Reactive Polyfluorinated Hypervalent Iodine(III) Compound

Hyper‐reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one‐pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well‐established reactions (e.g. C–C bond cleavage and the conversion of alco...

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Veröffentlicht in:Angewandte Chemie International Edition 2010-04, Vol.49 (15), p.2786-2789
Hauptverfasser: Schäfer, Sascha, Wirth, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
fluorine
homogeneous catalysis
hypervalent compounds
iodine
kinetics
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Beschreibung
Zusammenfassung:Hyper‐reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one‐pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well‐established reactions (e.g. C–C bond cleavage and the conversion of alcohols into aldehydes).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200907134