Highly efficient recyclable hydrated-clay supported catalytic system for atom transfer radical polymerization

Atom transfer radical polymerization of methacrylates has been performed using hydrated natural clay as a support for a CuBr(2)-ligand complex and the supported clay catalyst has been recycled for 21 batch polymerizations without losing its activity.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (30), p.4518-4520
Hauptverfasser: Munirasu, Selvaraj, Aggarwal, Ravi, Baskaran, Durairaj
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
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Zusammenfassung:Atom transfer radical polymerization of methacrylates has been performed using hydrated natural clay as a support for a CuBr(2)-ligand complex and the supported clay catalyst has been recycled for 21 batch polymerizations without losing its activity.
ISSN:1359-7345
1364-548X
DOI:10.1039/b908118f