Annulation of Tetrathiafulvalene to the Bay Region of Perylenediimide

A tetrathiafulvalene donor has been annulated to the bay region of perylenediimide affording a new π-conjugated molecular dyad. Various electronic excited charge-transfer states are generated in different oxidation states, leading to almost full absorption in the visible to near-IR region with a hig...

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Veröffentlicht in:	Organic letters 2010-03, Vol.12 (6), p.1344-1347
Hauptverfasser:	Jaggi, Michael, Blum, Carmen, Marti, Basil S, Liu, Shi-Xia, Leutwyler, Samuel, Decurtins, Silvio
Format:	Artikel
Sprache:	eng
Schlagworte:	Computer Simulation Fluorescent Dyes - chemical synthesis Fluorescent Dyes - chemistry Heterocyclic Compounds - chemistry Imides - chemistry Models, Chemical Molecular Structure Oxidation-Reduction Perylene - analogs & derivatives Perylene - chemistry
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Beschreibung
Zusammenfassung:	A tetrathiafulvalene donor has been annulated to the bay region of perylenediimide affording a new π-conjugated molecular dyad. Various electronic excited charge-transfer states are generated in different oxidation states, leading to almost full absorption in the visible to near-IR region with a high extinction coefficient.
ISSN:	1523-7060 1523-7052
DOI:	10.1021/ol1002708