Photochromism of spiropyrans and spirooxazines in the solid state: low temperature enhances photocoloration

In this study we have revealed that spiropyrans and spirooxazines, which have long been believed to be non-photochromic in the solid state, are generally photochromic in the solid state at least at low temperatures and that their photoreactivity increases greatly as the temperature is lowered.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (15), p.2593-2595
Hauptverfasser: Harada, Jun, Kawazoe, Yuta, Ogawa, Keiichiro
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this study we have revealed that spiropyrans and spirooxazines, which have long been believed to be non-photochromic in the solid state, are generally photochromic in the solid state at least at low temperatures and that their photoreactivity increases greatly as the temperature is lowered.
ISSN:1359-7345
1364-548X
DOI:10.1039/b925514a