Concise Approach to Pupukeanane Skeleton: Synthetic Study of Chloropupukeananin

Concise Approach to Pupukeanane Skeleton: Synthetic Study of Chloropupukeananin

A concise synthesis of a highly functionalized chloropupukeananin (1) skeleton via a reverse electron-demand Diels−Alder reaction and intramolecular carbonyl-ene reaction sequence based on our proposed biosynthetic pathway is described.

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Veröffentlicht in:Organic letters 2010-07, Vol.12 (13), p.2920-2923
Hauptverfasser: Suzuki, Takahiro, Kobayashi, Susumu
Format: Artikel
Sprache:eng
Schlagworte:
Molecular Structure
Sesquiterpenes - chemical synthesis
Sesquiterpenes - chemistry
Stereoisomerism
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Zusammenfassung:A concise synthesis of a highly functionalized chloropupukeananin (1) skeleton via a reverse electron-demand Diels−Alder reaction and intramolecular carbonyl-ene reaction sequence based on our proposed biosynthetic pathway is described.
ISSN:1523-7060
1523-7052
DOI:10.1021/ol100935w