Sequential insertion of three different organometallics into a versatile building block containing a PNA backbone

Sequential insertion of three different organometallics into a versatile building block containing a PNA backbone

In the view of developing a synthetic route for the controlled insertion of distinct organometallic moieties into peptide nucleic acid (PNA) oligomers, a proof-of-principle study of the chemoselective insertion of three different organometallics into a building block containing both a PNA backbone a...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (24), p.5617-5619
Hauptverfasser: Patra, Malay, Gasser, Gilles, Bobukhov, Dmytro, Merz, Klaus, Shtemenko, Alexander V, Metzler-Nolte, Nils
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Alkynes - chemistry
Backbone
Blocking
Crystallography, X-Ray
Insertion
Metalorganic compounds
Molecular Conformation
Nucleic acids
Oligomers
Organometallic Compounds - chemistry
Peptide Nucleic Acids - chemistry
Prints
Rhenium - chemistry
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Beschreibung
Zusammenfassung:In the view of developing a synthetic route for the controlled insertion of distinct organometallic moieties into peptide nucleic acid (PNA) oligomers, a proof-of-principle study of the chemoselective insertion of three different organometallics into a building block containing both a PNA backbone and an alkyne side-chain is presented in this study.
ISSN:1477-9226
1477-9234
DOI:10.1039/c003598j