Compressibility of solid c60

Room-temperature powder x-ray diffraction profiles have been obtained at hydrostatic pressures P = 0 and 1.2 gigapascals on the solid phase of cubic C(60) ("fullerite"). Within experimental error, the linear compressibility d(ln a)/dP is the same as the interlayer compressibility d(ln c)/d...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1991-05, Vol.252 (5010), p.1288-1290
Hauptverfasser: Fischer, J E, Heiney, P A, McGhie, A R, Romanow, W J, Denenstein, A M, McCauley, Jr, J P, Smith, 3rd, A B
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Sprache:eng
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Zusammenfassung:Room-temperature powder x-ray diffraction profiles have been obtained at hydrostatic pressures P = 0 and 1.2 gigapascals on the solid phase of cubic C(60) ("fullerite"). Within experimental error, the linear compressibility d(ln a)/dP is the same as the interlayer compressibility d(ln c)/dP of hexagonal graphite, consistent with van der Waals intermolecular bonding. The volume compressibility -d(ln V)/dP is 7.0 +/- 1 x 10(-12) square centimeter per dyne, 3 and 40 times the values for graphite and diamond, respectively.
ISSN:0036-8075
1095-9203
DOI:10.1126/science.252.5010.1288