Asymmetric Adsorption of Alanine by Quartz

Radioactive D- and L-alanine hydrochloride in 10$^{-5}$ molar dimethylformamide solution was adsorbed by d- and l-quartz to the extent of 20 to 30 percent, as shown by radioactivity loss. d-Quartz preferentially adsorbs D-alanine and l-quartz adsorbs L-alanine. The extent of asymmetric preferential...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1974-10, Vol.186 (4159), p.143-144
Hauptverfasser: Bonner, William A., Kavasmaneck, Percy R., Martin, Forrest S., Flores, Jose J.
Format: Artikel
Sprache:eng
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Zusammenfassung:Radioactive D- and L-alanine hydrochloride in 10$^{-5}$ molar dimethylformamide solution was adsorbed by d- and l-quartz to the extent of 20 to 30 percent, as shown by radioactivity loss. d-Quartz preferentially adsorbs D-alanine and l-quartz adsorbs L-alanine. The extent of asymmetric preferential adsorption is about 1.0 to 1.8 percent, at the 99.9 percent confidence level.
ISSN:0036-8075
1095-9203
DOI:10.1126/science.186.4159.143