Total Synthesis of (+)-Strictifolione
The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4‘, and C6‘ and a cross-methathesis to control the configuration of the double bond at C1‘−C2‘.
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| Veröffentlicht in: | Organic letters 2003-05, Vol.5 (11), p.1995-1997 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis of (+)-strictifolione was achieved from 3-phenylproprionaldehyde by using enantioselective allyltitanations to control the stereogenic centers at C6, C4‘, and C6‘ and a cross-methathesis to control the configuration of the double bond at C1‘−C2‘. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol034619s |