The Los Alamos Neutron Science Center neutron rheometer in the cone and plate geometry to examine tethered polymers/polymer melt interfaces via neutron reflectivity

Although several other neutron rheometers have been built to study soft matter under nonequilibrium conditions, none of them have the ability to measure the structure and behavior of the polymeric interfacial regions in highly viscous polymer melts which require high torques/high strain rates and high temperatures. A neutron rheometer in the cone and plate geometry has been constructed at the Los Alamos Neutron Science Center to rectify this lack of experimental instrumentation. It is also the first-of-its-kind to perform neutron reflectivity studies concurrently with rheological measurements. The details of both the development and testing of the Los Alamos Neutron Science Center neutron rheometer in the cone and plate configuration are described. Proof of principle neutron reflectivity results of end-grafted polystyrene against an identical melt under shear are presented, showing qualitatively that the structural attributes of the end-grafted polymer change when exposed to shear.