Chair−Boat Form Transformation of Piperazine-Containing Ligand toward the Preparation of Dirhenium Metallacycles

Chair−Boat Form Transformation of Piperazine-Containing Ligand toward the Preparation of Dirhenium Metallacycles

A new generation of a flexible bipyridine-based ligand, 1,4-bis(4-pyridyl)-piperazine, with two main stable states (chair and twist-boat forms) was employed in the construction of unusual dirhenium metallacycles.

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Veröffentlicht in:Inorganic chemistry 2009-07, Vol.48 (14), p.6329-6331
Hauptverfasser: Lee, Chung-Chou, Hsu, Shu-Chun, Lai, Long-Li, Lu, Kuang-Lieh
Format: Artikel
Sprache:eng
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Zusammenfassung:A new generation of a flexible bipyridine-based ligand, 1,4-bis(4-pyridyl)-piperazine, with two main stable states (chair and twist-boat forms) was employed in the construction of unusual dirhenium metallacycles.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic900040a