Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-05 (9), p.1036-1037
Hauptverfasser: Shin, Dong Mok, Lee, In Su, Chung, Young Keun, Lah, Myoung Soo
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Lee, In Su
Chung, Young Keun
Lah, Myoung Soo
description Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.
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source Royal Society Of Chemistry Journals; Royal Society of Chemistry Journals Archive (1841-2007); Alma/SFX Local Collection
title Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers
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