Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-05 (9), p.1036-1037
Hauptverfasser: Shin, Dong Mok, Lee, In Su, Chung, Young Keun, Lah, Myoung Soo
Format: Artikel
Sprache:eng
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Zusammenfassung:Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.
ISSN:1359-7345
DOI:10.1039/b210320f