Bis(O-ethyl di­thio­carbonato-κ2S,S′)­palladium(II)

Bis(O-ethyl di­thio­carbonato-κ2S,S′)­palladium(II)

The Pd atom in the title compound, [Pd(C3H5OS2)2], lies on an inversion center and adopts a square‐planar coordination geometry defined by the four S atoms of the two di­thio­carbonate (xanthate) ligands. In the solid state, the mol­ecules aggregate into layers in which the rows of mol­ecules altern...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-05, Vol.59 (5), p.m199-m200
Hauptverfasser: Ara, Irene, El Bahij, Fatima, Lachkar, Mohamed, Ben Larbi, Najib
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The Pd atom in the title compound, [Pd(C3H5OS2)2], lies on an inversion center and adopts a square‐planar coordination geometry defined by the four S atoms of the two di­thio­carbonate (xanthate) ligands. In the solid state, the mol­ecules aggregate into layers in which the rows of mol­ecules alternate their orientation to allow each Pd atom to interact with two symmetry‐equivalent S atoms of the xanthate ligands of adjacent mol­ecules, generating a pseudo‐octahedral environment around each Pd atom. This weak interaction of 3.3579 (7) Å can be classified as a closed‐shell electrostatic intermolecular interaction.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103007406