trans-Bis­(di­methyl­glyoximato-κ2N,N′)­(1-hexenyl)(pyridine-κN)­cobalt(III): a cobaloxime-substituted terminal alkene that rapidly isomerizes to a cobaloxime-substituted internal alkenyl complex

An unusual cobaloxime‐substituted terminal alkene, [Co(C6H11)(C4H7N2O2)2(C5H5N)], has been isolated and characterized by X‐ray crystallography. The double bond in the alkene readily isomerizes, but the title compound could be isolated and structurally characterized at low temperature.

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-05, Vol.59 (5), p.m193-m195
Hauptverfasser: Pickin, Kerry A., Day, Cyn­thia S., Wright, Marcus W., Welker, Mark E.
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Sprache:eng
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