trans-Bis­(di­methyl­glyoximato-κ2N,N′)­(1-hexenyl)(pyridine-κN)­cobalt(III): a cobaloxime-substituted terminal alkene that rapidly isomerizes to a cobaloxime-substituted internal alkenyl complex

trans-Bis­(di­methyl­glyoximato-κ2N,N′)­(1-hexenyl)(pyridine-κN)­cobalt(III): a cobaloxime-substituted terminal alkene that rapidly isomerizes to a cobaloxime-substituted internal alkenyl complex

An unusual cobaloxime‐substituted terminal alkene, [Co(C6H11)(C4H7N2O2)2(C5H5N)], has been isolated and characterized by X‐ray crystallography. The double bond in the alkene readily isomerizes, but the title compound could be isolated and structurally characterized at low temperature.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2003-05, Vol.59 (5), p.m193-m195
Hauptverfasser: Pickin, Kerry A., Day, Cyn­thia S., Wright, Marcus W., Welker, Mark E.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:An unusual cobaloxime‐substituted terminal alkene, [Co(C6H11)(C4H7N2O2)2(C5H5N)], has been isolated and characterized by X‐ray crystallography. The double bond in the alkene readily isomerizes, but the title compound could be isolated and structurally characterized at low temperature.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103006899