The Total Synthesis of Racemic Teucvin and 12-epi-Teucvin

The Total Synthesis of Racemic Teucvin and 12-epi-Teucvin

Complete face‐, stereo‐, and regioselectivity in the Diels–Alder reaction of compounds 1 and 2 was the key to the first total synthesis, in racemic form, of the 19‐norclerodane diterpenoids teucvin and 12‐epi‐teucvin.

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Veröffentlicht in:Angewandte Chemie International Edition 2003-04, Vol.42 (16), p.1851-1853
Hauptverfasser: Liu, Hsing-Jang, Zhu, Jia-Liang, Chen, I-Chia, Jankowska, Renata, Han, Yongxin, Shia, Kak-Shan
Format: Artikel
Sprache:eng
Schlagworte:
Diels-Alder reaction
natural products
terpenoids
teucvin
total synthesis
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Zusammenfassung:Complete face‐, stereo‐, and regioselectivity in the Diels–Alder reaction of compounds 1 and 2 was the key to the first total synthesis, in racemic form, of the 19‐norclerodane diterpenoids teucvin and 12‐epi‐teucvin.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200250681