Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age

Structural and electronic properties associated with donor ligands that contain 'spectator' transition-metal fragments are analyzed. The current status of such non-ferrocenyl chiral bidentate ligands is reviewed from the standpoint of synthesis, applications in metal-catalyzed enantioselec...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-03 (6), p.665-675
Hauptverfasser: Delacroix, Olivier, Gladysz, John A
Format: Artikel
Sprache:eng
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Zusammenfassung:Structural and electronic properties associated with donor ligands that contain 'spectator' transition-metal fragments are analyzed. The current status of such non-ferrocenyl chiral bidentate ligands is reviewed from the standpoint of synthesis, applications in metal-catalyzed enantioselective reactions, and future directions.
ISSN:1359-7345
1364-548X
DOI:10.1039/b207963c