Photoresponsive Nanocomposite Formed by Self-Assembly of an Azobenzene-Modified Silane

Organization of photoresponsive azobenzene ligands within a 3D porous framework imparts new molecular‐level functionality. The trans⇌cis conformation change of azobenzene ligands triggered by photoirradiation transduces photo energy into mechanical work, which can be used for opening and closing val...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-04, Vol.42 (15), p.1731-1734
Hauptverfasser: Liu, Nanguo, Chen, Zhu, Dunphy, Darren R., Jiang, Ying-Bing, Assink, Roger A., Brinker, C. Jeffrey
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Sprache:eng
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Zusammenfassung:Organization of photoresponsive azobenzene ligands within a 3D porous framework imparts new molecular‐level functionality. The trans⇌cis conformation change of azobenzene ligands triggered by photoirradiation transduces photo energy into mechanical work, which can be used for opening and closing valves (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200250189