P[N(i-Bu)CH2CH2]3N: A Versatile Ligand for the Pd-Catalyzed Amination of Aryl Chlorides
Palladium-catalyzed amination reactions of aryl chlorides with amines proceeded in the presence of the bicyclic triaminophosphine P[N(i-Bu)CH2CH2]3N to afford the corresponding arylamines in good to excellent yields. Electron-poor, electron-neutral, and electron-rich aryl chlorides all participated...
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| Veröffentlicht in: | Organic letters 2003-03, Vol.5 (6), p.815-818 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Palladium-catalyzed amination reactions of aryl chlorides with amines proceeded in the presence of the bicyclic triaminophosphine P[N(i-Bu)CH2CH2]3N to afford the corresponding arylamines in good to excellent yields. Electron-poor, electron-neutral, and electron-rich aryl chlorides all participated with equal ease. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol027450b |