New Tricks for an Old Dog: The Carbonate Ion as a Building Block for Networks Including Examples of Composition [Cu6(CO3)12{C(NH2)3}8]4− with the Sodalite Topology

New Tricks for an Old Dog: The Carbonate Ion as a Building Block for Networks Including Examples of Composition [Cu6(CO3)12{C(NH2)3}8]4− with the Sodalite Topology

Cupric ions and carbonate ions, under the templating influence of pairs of hydrogen‐bonding guanidinium ions, associate to form an infinite network with the topology of the 4264 sodalite net. This cage structure (see picture; for clarity, only copper centers and carbonate ions are shown) offers grea...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-03, Vol.42 (10), p.1112-1115
Hauptverfasser: Abrahams, Brendan F., Haywood, Marissa G., Robson, Richard, Slizys, Damian A.
Format: Artikel
Sprache:eng
Schlagworte:
cage compounds
carbonates
coordination polymers
guanidinium ion
sodalite
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Beschreibung
Zusammenfassung:Cupric ions and carbonate ions, under the templating influence of pairs of hydrogen‐bonding guanidinium ions, associate to form an infinite network with the topology of the 4264 sodalite net. This cage structure (see picture; for clarity, only copper centers and carbonate ions are shown) offers great scope for crystal engineering.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200390292