Chiral-Mn(Salen)-Complex-Catalyzed Kinetic Resolution of Secondary Alcohols in Water

Chiral-Mn(Salen)-Complex-Catalyzed Kinetic Resolution of Secondary Alcohols in Water

A mild, green method for enantioselective kinetic resolution of secondary alcohols has been developed using Mn(salen) complexes as catalysts in water. Up to 97.8 % ee was attained. PTC=phase‐transfer catalyst.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2003-03, Vol.42 (9), p.1042-1044
Hauptverfasser: Sun, Wei, Wang, Hongwang, Xia, Chungu, Li, Jingwei, Zhao, Peiqing
Format: Artikel
Sprache:eng
Schlagworte:
alcohols
green chemistry
kinetic resolution
manganese complexes
salen ligands
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A mild, green method for enantioselective kinetic resolution of secondary alcohols has been developed using Mn(salen) complexes as catalysts in water. Up to 97.8 % ee was attained. PTC=phase‐transfer catalyst.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200390268