Photochemical and thermal ligand exchange in a ruthenium(II) complex based on a scorpionate terpyridine ligand
A ruthenium(II) complex containing a 1,10-phenanthroline unit and a terpyridine fragment covalently linked to a benzonitrile group has been synthesised; coordination and decoordination of the benzonitrile group can be induced thermally and photochemically respectively, in an acetone-water mixture.
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2003-01 (2), p.188-189 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A ruthenium(II) complex containing a 1,10-phenanthroline unit and a terpyridine fragment covalently linked to a benzonitrile group has been synthesised; coordination and decoordination of the benzonitrile group can be induced thermally and photochemically respectively, in an acetone-water mixture. |
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| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/b210607h |