Chiral reagents for the determination of enantiomeric excess and absolute configuration using NMR spectroscopy

Chiral reagents for the determination of enantiomeric excess and absolute configuration using NMR spectroscopy

Recent advances in the development of chiral derivatizing and solvating agents that facilitate the determination of enantiomeric excess and absolute configuration are reviewed. These include metal‐containing species, host–guest systems, donor–acceptor compounds, and liquid crystal discriminating age...

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Veröffentlicht in:Chirality (New York, N.Y.) N.Y.), 2003, Vol.15 (3), p.256-270
Hauptverfasser: Wenzel, Thomas J., Wilcox, James D.
Format: Artikel
Sprache:eng
Schlagworte:
absolute configuration
chiral derivatizing agent
chiral shift reagents
chiral solvating agent
enantiomeric excess
NMR
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Zusammenfassung:Recent advances in the development of chiral derivatizing and solvating agents that facilitate the determination of enantiomeric excess and absolute configuration are reviewed. These include metal‐containing species, host–guest systems, donor–acceptor compounds, and liquid crystal discriminating agents. In the aggregate, these reagents can be used to analyze a wide range of compound classes. Chirality 15:256–270, 2003. © 2003 Wiley‐Liss, Inc.
ISSN:0899-0042
1520-636X
DOI:10.1002/chir.10190