Sulfonic acid-functionalized silica through quantitative oxidation of thiol groups

A simple procedure for the preparation of amorphous silica containing thiol groups which quantitatively affords sulfonic acid groups has been developed, resulting in site densities and activity for the esterification of acetic acid with methanol greater than a commercial Nafion silica composite.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2003-01 (2), p.246-247
Hauptverfasser: Cano-Serrano, E, Campos-Martin, J M, Fierro, J L G
Format: Artikel
Sprache:eng
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Zusammenfassung:A simple procedure for the preparation of amorphous silica containing thiol groups which quantitatively affords sulfonic acid groups has been developed, resulting in site densities and activity for the esterification of acetic acid with methanol greater than a commercial Nafion silica composite.
ISSN:1359-7345
1364-548X
DOI:10.1039/b210766j