Catalytic Oxidation of Alcohols in Water under Atmospheric Oxygen by Use of an Amphiphilic Resin-Dispersion of a Nanopalladium Catalyst

Catalytic Oxidation of Alcohols in Water under Atmospheric Oxygen by Use of an Amphiphilic Resin-Dispersion of a Nanopalladium Catalyst

A step closer to the ideal oxidation of alcohols: Catalytic oxidation of alcohols in water under atmospheric oxygen was achieved by use of an amphiphilic resin‐dispersion of a nanopalladium catalyst (see scheme). This system combines high catalytic activity owing to the large surface area of the nan...

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Veröffentlicht in:Angewandte Chemie International Edition 2003-01, Vol.42 (2), p.194-197
Hauptverfasser: Uozumi, Yasuhiro, Nakao, Ryu
Format: Artikel
Sprache:eng
Schlagworte:
catalysts
nanoparticles
oxidation
palladium
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Zusammenfassung:A step closer to the ideal oxidation of alcohols: Catalytic oxidation of alcohols in water under atmospheric oxygen was achieved by use of an amphiphilic resin‐dispersion of a nanopalladium catalyst (see scheme). This system combines high catalytic activity owing to the large surface area of the nanoparticles and water‐based reactivity provided by the amphiphilicity of the polystyrene—poly(ethylene glycol) matrix.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200390076