Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure

Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber−Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodica...

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Veröffentlicht in:Journal of the American Chemical Society 2003-01, Vol.125 (2), p.334-335
Hauptverfasser: Murakami, Tsuyoshi, Nishikiori, Tokujiro, Nohira, Toshiyuki, Ito, Yasuhiko
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container_title Journal of the American Chemical Society
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creator Murakami, Tsuyoshi
Nishikiori, Tokujiro
Nohira, Toshiyuki
Ito, Yasuhiko
description Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber−Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode.
doi_str_mv 10.1021/ja028891t
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Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...)
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
title Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure
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