Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure

Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure

Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber−Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodica...

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Veröffentlicht in:Journal of the American Chemical Society 2003-01, Vol.125 (2), p.334-335
Hauptverfasser: Murakami, Tsuyoshi, Nishikiori, Tokujiro, Nohira, Toshiyuki, Ito, Yasuhiko
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Elements and non-metal compounds (oxides, hydroxides, hydrides, sulfides, carbides, ...)
Exact sciences and technology
Inorganic chemistry and origins of life
Preparations and properties
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Zusammenfassung:Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber−Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja028891t