Direct organocatalytic aldol reactions in buffered aqueous media

Direct organocatalytic aldol reactions in buffered aqueous media

Organocatalytic cross-aldol reactions catalyzed by cyclic secondary amines in aqueous media provide a direct route to a variety of aldols including carbohydrate derivatives and may warrant consideration as a prebiotic route to sugars.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-01 (24), p.3024-3025
Hauptverfasser: Córdova, Armando, Notz, Wolfgang, Barbas, 3rd, Carlos F
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes - chemistry
Amines - chemistry
Buffers
Catalysis
Chemistry, Organic - methods
Ketones - chemistry
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Zusammenfassung:Organocatalytic cross-aldol reactions catalyzed by cyclic secondary amines in aqueous media provide a direct route to a variety of aldols including carbohydrate derivatives and may warrant consideration as a prebiotic route to sugars.
ISSN:1359-7345
1364-548X
DOI:10.1039/b207664k