Novel template effect for the preparation of [2]rotaxanes with functionalised centre pieces

Novel template effect for the preparation of [2]rotaxanes with functionalised centre pieces

A novel anion-templated synthesis permits the preparation of [2]rotaxanes with a tetralactam wheel through which axles are threaded that are functionalised at their center pieces; the wheel protects these groups efficiently against modifications.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2002-11 (22), p.2628-2629
Hauptverfasser: Ghosh, Pradyut, Mermagen, Oliver, Schalley, Christoph A
Format: Artikel
Sprache:eng
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Zusammenfassung:A novel anion-templated synthesis permits the preparation of [2]rotaxanes with a tetralactam wheel through which axles are threaded that are functionalised at their center pieces; the wheel protects these groups efficiently against modifications.
ISSN:1359-7345
DOI:10.1039/b208361b