Intermolecular Rhodium(II)-Catalyzed Reactions with Silicon-Substituted Carbonyl Ylides
The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyl-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield.
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| Veröffentlicht in: | Organic letters 2002-12, Vol.4 (26), p.4631-4633 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The Rh(II)-catalyzed reaction of benzyl 2-trialkylsilyl-2-diazoacetates with various acyclic and cyclic ketones affords novel dioxolanones via silicon-substituted carbonyl ylides in up to 98% yield. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol026987m |