A Highly Efficient Catalyst for the Telomerization of 1,3-Dienes with Alcohols: First Synthesis of a Monocarbenepalladium(0)-Olefin Complex

A Highly Efficient Catalyst for the Telomerization of 1,3-Dienes with Alcohols: First Synthesis of a Monocarbenepalladium(0)-Olefin Complex

Industrial reaction improved: The first monocarbenepalladium(0)–olefin complex has been isolated and characterized (see structure; Pd orange, N green, S yellow, O blue). The complex exhibited unprecedented high catalyst productivity and selectivity for industrially important telomerization reactions...

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Veröffentlicht in:Angewandte Chemie International Edition 2002-03, Vol.41 (6), p.986-989
Hauptverfasser: Jackstell, Ralf, Gómez Andreu, Mario, Frisch, Anja, Selvakumar, Kumaravel, Zapf, Alexander, Klein, Holger, Spannenberg, Anke, Röttger, Dirk, Briel, Oliver, Karch, Ralf, Beller, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
carbene ligands
homogeneous catalysis
palladium
telomerization
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Zusammenfassung:Industrial reaction improved: The first monocarbenepalladium(0)–olefin complex has been isolated and characterized (see structure; Pd orange, N green, S yellow, O blue). The complex exhibited unprecedented high catalyst productivity and selectivity for industrially important telomerization reactions (the dimerization of 1,3‐dienes in the presence of a nucleophile, in this case an alcohol).
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20020315)41:6<986::AID-ANIE986>3.0.CO;2-M