Theory of nonlinear rheology and yielding of dense colloidal suspensions

A first-principles approach to the nonlinear flow of dense suspensions is presented which captures shear thinning of colloidal fluids and dynamical yielding of colloidal glasses. The advection of density fluctuations plays a central role, suppressing the caging of particles and speeding up structura...

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Veröffentlicht in:Physical review letters 2002-12, Vol.89 (24), p.248304-248304, Article 248304
Hauptverfasser: Fuchs, Matthias, Cates, Michael E
Format: Artikel
Sprache:eng
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Zusammenfassung:A first-principles approach to the nonlinear flow of dense suspensions is presented which captures shear thinning of colloidal fluids and dynamical yielding of colloidal glasses. The advection of density fluctuations plays a central role, suppressing the caging of particles and speeding up structural relaxation. A mode coupling approach is developed to explore these effects.
ISSN:0031-9007
1079-7114
DOI:10.1103/physrevlett.89.248304