QMOF-1 and QMOF-2: Three-Dimensional Metal-Organic Open Frameworks with a Quartzlike Topology

QMOF-1 and QMOF-2: Three-Dimensional Metal-Organic Open Frameworks with a Quartzlike Topology

Man‐made minerals: The synthesis of two α‐ and β‐quartz structures with open metal–organic frameworks (QMOF‐1 and QMOF‐2) is reported. QMOF‐1 is assigned to Zn(ISN)2⋅2 H2O (ISN=isonicotinic acid) with the low symmetry of α‐quartz, while QMOF‐2 to InH(BDC)2 (BDC=terephthalate) with the high symmetry...

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Veröffentlicht in:Angewandte Chemie International Edition 2002-12, Vol.41 (23), p.4471-4473
Hauptverfasser: Sun, Jinyu, Weng, Linhong, Zhou, Yaming, Chen, Jinxi, Chen, Zhenxia, Liu, Zhicheng, Zhao, Dongyuan
Format: Artikel
Sprache:eng
Schlagworte:
carboxylate ligands
chirality
coordination polymers
microporus materials
supramolecular chemistry
zeolite analogues
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Zusammenfassung:Man‐made minerals: The synthesis of two α‐ and β‐quartz structures with open metal–organic frameworks (QMOF‐1 and QMOF‐2) is reported. QMOF‐1 is assigned to Zn(ISN)2⋅2 H2O (ISN=isonicotinic acid) with the low symmetry of α‐quartz, while QMOF‐2 to InH(BDC)2 (BDC=terephthalate) with the high symmetry of β‐quartz.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20021202)41:23<4471::AID-ANIE4471>3.0.CO;2-9