Copper-Catalyzed Reductive Alkylations of Enones: A Novel Transmetalation Protocol
Looking for an alternative to prepare your regio‐ and stereodefined boron enolates? Concerned about using expensive and moisture‐sensitive Bu2BOTf? Consider this new procedure for regiospecific enolization based on a catalytic CuH‐initiated 1,4‐reduction followed by in situ transmetalation with a si...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2002-12, Vol.41 (23), p.4580-4582 |
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| container_issue | 23 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 41 |
| creator | Lipshutz, Bruce H. Papa, Patrick |
| description | Looking for an alternative to prepare your regio‐ and stereodefined boron enolates? Concerned about using expensive and moisture‐sensitive Bu2BOTf? Consider this new procedure for regiospecific enolization based on a catalytic CuH‐initiated 1,4‐reduction followed by in situ transmetalation with a simple borane (R$\rm{^{{\prime}}_{{2}}}$BH; see scheme). |
| doi_str_mv | 10.1002/1521-3773(20021202)41:23<4580::AID-ANIE4580>3.0.CO;2-7 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | boron copper hydrides reduction transmetalation |
| title | Copper-Catalyzed Reductive Alkylations of Enones: A Novel Transmetalation Protocol |
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