trans-Addition of Two Carbon Substituents across a Benzene Double Bond in [(η6-Benzene)Mo(CO)3]

trans-Addition of Two Carbon Substituents across a Benzene Double Bond in [(η6-Benzene)Mo(CO)3]

No CO insertion occurs in the first Mo(CO)3‐mediated dearomatization reaction sequence (shown). In contrast to the analogous Cr(CO)3 reaction, the intermediate allyl complex can be isolated.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2002-12, Vol.41 (23), p.4577-4579
Hauptverfasser: Kündig, E. Peter, Fabritius, Charles-H., Grossheimann, Gabriele, Robvieux, Fabrice, Romanens, Patrick, Bernardinelli, Gérald
Format: Artikel
Sprache:eng
Schlagworte:
allylation
arene ligands
molybdenum
nucleophilic addition
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Beschreibung
Zusammenfassung:No CO insertion occurs in the first Mo(CO)3‐mediated dearomatization reaction sequence (shown). In contrast to the analogous Cr(CO)3 reaction, the intermediate allyl complex can be isolated.
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20021202)41:23<4577::AID-ANIE4577>3.0.CO;2-4