Stereoselective Intermolecular Carboazidation of Chiral Allylsilanes
Easily available chiral allylsilanes were used as substrate for carboazidation reactions. For the first time, a substantial control of the stereochemistry of the azidation of acyclic nonconjugated radicals was achieved.
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| Veröffentlicht in: | Organic letters 2002-11, Vol.4 (24), p.4257-4260 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Easily available chiral allylsilanes were used as substrate for carboazidation reactions. For the first time, a substantial control of the stereochemistry of the azidation of acyclic nonconjugated radicals was achieved. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/ol026824y |